Marcel Swart Spin States in Biochemistry and Inorganic Chemistry. Influence on Structure and Reactivity

author Marcel Swart
isbn 9781118898307
13003.06 РУБ
Описание:

it is essential to understand the important role of spin states in influencing molecular structure, and these methods are applied in studies throughout the book. As the fields of inorganic chemistry and catalysis move towards the use of cheap, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, biophysics and pharmaceutical chemistry. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, non-toxic first row transition metals, spin-crossover materials, bonding and reactivity.. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, catalysis, organometallic chemistry, Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, materials science, in industrial catalysis and in spin crossover compounds, ligand-field theory and coupled cluster theory are discussed, and the use of NMR for the analysis of spin densities is described.It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules



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Marcel Swart Spin States in Biochemistry and Inorganic Chemistry. Influence on Structure and Reactivity

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